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The Chemistry of α,β-Unsaturated Ethers. V. Diels-Alder Reaction of Paraformaldehyde and 1-Alkoxy-1,3-alkadienes 1

✍ Scribed by Kubler, D. G.


Book ID
126933487
Publisher
American Chemical Society
Year
1962
Tongue
English
Weight
248 KB
Volume
27
Category
Article
ISSN
0022-3263

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✍ A. A. Broekhuis; J. W. Scheeren; R. J. F. Nivard 📂 Article 📅 2010 🏛 Elsevier Science 🌐 English ⚖ 643 KB

## Abstract Effects of substituents in diene and dienophile on the regio‐ and stereo‐selectivity of Diels‐Alder reactions have been studied on cycloadditions of alkoxy‐substituted 1,3‐butadienes (**1**) and 2‐substituted cyanoethenes (**2**). The regioselectivity is always very high, and is determi