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The Chemistry of Xylylenes. XX. The Gas Phase Oxidation of p-Methylbenzyl Radicals and p-Xylylene

✍ Scribed by Errede, L. A.; English, W. D.


Book ID
127092608
Publisher
American Chemical Society
Year
1963
Tongue
English
Weight
618 KB
Volume
28
Category
Article
ISSN
0022-3263

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📜 SIMILAR VOLUMES


The chemistry of xylylenes. XIII. The pr
✍ Errede, L. A. ;Gregorian, R. S. 📂 Article 📅 1962 🏛 John Wiley and Sons ⚖ 726 KB

## Abstract The problem of crystallinity and crosslinking in poly(__p__‐xylylene) was re‐investigated with the use of polymer that was prepared by polymerization of __p__‐xylylene in solution. It was found that amorphous polymer is converted irreversibly to α‐crystalline polymer at 50–140°C. The α‐

The chemistry of xylylenes. XIV. The mol
✍ Errede, L. A. ;Knoll, N. 📂 Article 📅 1962 🏛 John Wiley and Sons ⚖ 595 KB

## Abstract Freshly prepared α‐poly(__p__‐xylylene) softens at 220–260°C. and then rehardens as it forms β‐poly(__p__‐xylylene). Consequently, homogeneous objects can be fabricated at this temperature range by simultaneous application of heat and pressure. This “moldable” poly(__p__‐xylylene), howe

The vacuum and oxidative pyrolysis of po
✍ Jellinek, H. H. G. ;Lipovac, S. N. 📂 Article 📅 1970 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 696 KB

## Abstract Poly‐__p__‐xylylene prepared by pyrolysis of di‐__p__‐xylylene has been degraded under vacuum and in the presence of oxygen as a function of temperature and oxygen pressure. The vacuum pyrolysis is mainly due to “abnormal” structures. Volatiles are initially produced quite slowly, but t