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The chemistry of vicinal tricarbonyls. A stable vinyl tricarbonyl hydrate as a di- and trielectrophile

✍ Scribed by Wasserman, Harry H.; Fukuyama, James; Murugesan, Natesan; Van Duzer, John; Lombardo, Louis; Rotello, Vincent; McCarthy, Keith


Book ID
127144695
Publisher
American Chemical Society
Year
1989
Tongue
English
Weight
242 KB
Volume
111
Category
Article
ISSN
0002-7863

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The Smallest Vicinal Tricarbonyl Compoun
✍ Shyamaprosad Goswami; Annada C. Maity; Hoong-Kun Fun; Suchada Chantrapromma 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 850 KB

## Abstract An effective synthesis of 2‐oxo‐1,3‐propanedial monohydrate or mesoxaldehyde (**6a**) and the first synthesis of 2,3‐dioxo‐1,4‐butanedial (**18**) as a thiane derivative are reported. These first members of the smallest vicinal tri‐ and tetracarbonyl compounds are stabilized by conversi