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The Chemistry of the Spiroaminoketal Side Chain of Solasodine and Tomatidine. III. 1 The Reaction of O,N-Diacetylsolasodine in Acidic Media

✍ Scribed by SATO, YOSHIO; IKEKAWA, NOBUO


Book ID
126155076
Publisher
American Chemical Society
Year
1960
Tongue
English
Weight
376 KB
Volume
25
Category
Article
ISSN
0022-3263

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## Abstract In the autoxidation of cumenes to benzoic acids at about 140Β° in butyric acid as solvent and with Co‐ and Mn‐acetates as catalysts the main side‐reaction is the formation of dimethylbenzyl alcohols. It may be suppressed by employing a low hydrocarbon concentration. The carbinols formed