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The Chemistry of Sultones. III. Formation of Six- in Preference to Five-Membered Ring Sultones 1

✍ Scribed by Truce, William E.; Burdge, David N.; Steltenkamp, Robert J.


Book ID
126061536
Publisher
American Chemical Society
Year
1962
Tongue
English
Weight
474 KB
Volume
27
Category
Article
ISSN
0022-3263

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πŸ“œ SIMILAR VOLUMES


Six- versus five-membered ring formation
✍ Ana M. GΓ³mez; Marı́a D. Company; Clara Uriel; Serafı́n Valverde; J.CristΓ³bal LΓ³p πŸ“‚ Article πŸ“… 2002 πŸ› Elsevier Science 🌐 French βš– 74 KB

Radical cyclization of 1-vinyl-5-methyl-5-hexenyl radicals (radical numbering) affords six-membered ring products prevailing over the isomeric five-membered ring compounds; the former are generated through two reaction pathways: 6-endo-trig ring closure and rearrangement of intermediate methylenecyc