The Chemistry of Pyrrocorphins: C-Methylation of Pyrrocorphinates at the Ligand Periphery
✍ Scribed by Rudolf Waditschatka; Eva Diener; Prof. Dr. Albert Eschenmoser
- Book ID
- 101552643
- Publisher
- John Wiley and Sons
- Year
- 1983
- Tongue
- English
- Weight
- 229 KB
- Volume
- 22
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
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The alkyIation of enaminoltetones, I. warr reported by Leonad and Adamcik 1.2 to give rise too-alkylated salts, II. The latter was found to be readily displaced by nucleophiles (amines, thiola, etc. ) at the ring carbon to give a variety of substituted iminium salts, III. Ia a program a-d at studyin
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## Abstract Two ligands bearing the 2,6‐pyridinedicarboxamide unit, namely PyPSMeH~2~ and PyPOMeH~2~, have been used to prepare complexes of Fe^III^ which have been structurally characterised. The potentially pentadentate thioether ligand PyPSMeH~2~ affords only the bis complex (Et~4~N)[Fe(PyPSMe)~