The chemistry of O-silylated ketene acetal; Pummerer rearrangement of sulfoxides into α-siloxysulfides
✍ Scribed by Y. Kita; H. Yasuda; O. Tamura; F. Itoh; Y. Tamura
- Publisher
- Elsevier Science
- Year
- 1984
- Tongue
- French
- Weight
- 139 KB
- Volume
- 25
- Category
- Article
- ISSN
- 0040-4039
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📜 SIMILAR VOLUMES
## 1997 sulfoxides, sulfones, sulfenes and derivatives sulfoxides, sulfones, sulfenes and derivatives (benzene compounds) Q 0600 ## 44 -092 Enantioselective Pummerer-Type Rearrangement by Reaction of O-Silylated Ketene Acetal with Enantiopure α-Substituted Sulfoxides. -The sulfoxides (-)-(I) an
Diastereoselective carbon-carbon bond forming reaction of 2,3-O-isopropylidene-D (and L)-glyceraldehydes (D and L-2) with ketene silyl acetals (la,b) occurred in acetonitrile under mild conditions to give the-corresponding anti-P-siloxyesters (D and L-3a) as major products, which could be converted