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The chemistry of methyl and ethyl radicals on Pt(111) from the decomposition of tri-alkyl bismuth compounds

✍ Scribed by Maria E. Pansoy-Hjelvik; Robbie Xu; Quanyin Gao; Keith Weller; Frank Feher; John C. Hemminger


Book ID
118366820
Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
655 KB
Volume
312
Category
Article
ISSN
0039-6028

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Arrhenius parameters have been determined for the hydrogen-abstraction reactions: R + SiHCI, + RH + SiCl, CF, 323-46 1 5.98 & 0.06 11.77 f 0.03 8.50 CH, 333-443 4.30 f 0.08 10.83 & 0.04 8.48 C,H, 314-413 5.32 & 0.07 11.54 f 0.04 8.63 7 - l h e trend in activation energies ECH, < E c ~H , < ECF, is