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The Chemistry of Hydroperoxides. IX. Relative Migratory Aptitudes of Groups in free Radical Rearrangements

✍ Scribed by Kharasch, M. S.; Poshkus, Algirdas C.; Fono, Andrew; Nudenberg, W.

Book ID
111900216
Publisher
American Chemical Society
Year
1951
Tongue
English
Weight
945 KB
Volume
16
Category
Article
ISSN
0022-3263

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πŸ“œ SIMILAR VOLUMES

The Migratory Aptitude of the Ethoxycarb
The Migratory Aptitude of the Ethoxycarbonyl Group in the Pinacol Rearrangement. Preliminary communication
✍ Jacques Kagan; Dalmacio A. Agdeppa Jr.; S. P. Singh πŸ“‚ Article πŸ“… 1972 πŸ› John Wiley and Sons 🌐 German βš– 192 KB πŸ‘ 2 views

## Abstract The migratory aptitude of the ethoxycarbonyl group in the pinacol rearrangement was deduced from the structure of the products observed after treatment of 2‐substituted 2,3‐dihydroxy‐3‐phenylbutyrates with fluorosulfonic acid at 0Β° for 3 minutes. The migratory aptitude of ethoxycarbonyl