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THE CHEMISTRY OF HYDROPEROXIDES. IV. OXIDATION OF TERTIARY AROMATIC ALCOHOLS WITH HYDROGEN PEROXIDE OR HYDROPEROXIDES

โœ Scribed by KHARASCH, M. S.; FONO, ANDREW; NUDENBERG, W.; POSHKUS, ALGIRDAS C.


Book ID
120374531
Publisher
American Chemical Society
Year
1950
Tongue
English
Weight
538 KB
Volume
15
Category
Article
ISSN
0022-3263

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Oxidations by the system โ€œhydrogen perox
โœ Georgiy B Shul'pin; Georg Sรผss-Fink; John R Lindsay Smith ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 694 KB

Higher alkanes (cyclohexane, n-pentane, n-heptane, methylbutane, 2-and 3methylpentanes, 3-methylhexane, cis-and trans-deealins) are oxidized at 20 ยฐC by H202 in air in acetonitrile (or nitromethane) solution in the presence of the manganese(IV) salt [L2Mn203](PF6)2 (L = 1,4,7-trimethyl-1,4-7-triazac