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THE CHEMISTRY OF HYDROPEROXIDES. III. THE FREE-RADICAL DECOMPOSITION OF HYDROPEROXIDES

✍ Scribed by KHARASCH, M. S.; FONO, ANDREW; NUDENBERG, W.

Book ID
111987757
Publisher
American Chemical Society
Year
1950
Tongue
English
Weight
774 KB
Volume
15
Category
Article
ISSN
0022-3263

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## Abstract The HClO~4~‐catalyzed decomposition of a number of alkylbenzyl hydroperoxides has been investigated by a study of the reaction kinetics in 50% w ethanol at 50Β°C. A Hammett relation (__p__ = ‐4.57) has been found to exist for the decomposition of ring‐substituted Ξ±,α‐dimethylbenzyl hydro