The chemistry of D-gluconic acid derivatives. Part II1: The formation of (R)-O-isopropylideneglyceraldehyde from D-glucono-1,5-lactone
โ Scribed by Gordon J. F. Chittenden
- Publisher
- Elsevier Science
- Year
- 2010
- Tongue
- English
- Weight
- 345 KB
- Volume
- 107
- Category
- Article
- ISSN
- 0165-0513
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The interaction of n-glucono-1,54actone with monovalent ions has been studied in aqueous solution at neutral pH. The o-gluconate salts of Lit, Naf, K+, NH:, Rb+, and Csc were studied by 13C NMR, PT'IR, and by X-ray powder diffraction. The spectroscopic evidence suggests that in aqueous solution, th
The Winig rearrangement of D-galactono-y-lactone derived [~O-glycoside is shown to al't~rd [5-C-glycoside (retention product), a potentially useful intermediate tbr zaragozic acid synthesis. By contrast, the rearrangement of the D-xylonolactone-derived counterpart was found to violate the retention
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