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The chemical-transformation products of 1,6-dibromo-1,6-dideoxygalactitol and 1,2:5,6-dianhydrogalactitol in aqueous solution

✍ Scribed by Ildikó Vidra; Kálmán Simon; László Institóris; Ingeborg Csöregh; Mátyás Czugler


Publisher
Elsevier Science
Year
1982
Tongue
English
Weight
993 KB
Volume
111
Category
Article
ISSN
0008-6215

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✦ Synopsis


After hydrolysis of 1,6-dibromo-1,6dideoxygalactitol

(1) and 1,2 : 5,6-dianhydrogalactitol (2), 11 compounds were isolated, three of them as tritylated derivatives.


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The gas-phase clustering reactions of SF~, SF 6 and F-ions with SF 6 were measured using a high-pressure mass spectrometer. The bond energies of SFs--(SF6) 1 and SF6(SF6) 1 were estimated to be ~< 2.3 kcal/mol. The bond energies of F-(SF6) , with n = 1 and 2 were determined to be 5.4 and = 4.1 kcal/