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The chemical reactivity of some terpenes investigated by alumina catalyzed epoxidation with hydrogen peroxide and by DFT calculations

✍ Scribed by Juliana M. de S. e Silva; Fábio S. Vinhado; Dalmo Mandelli; Ulf Schuchardt; Roberto Rinaldi


Publisher
Elsevier Science
Year
2006
Tongue
English
Weight
501 KB
Volume
252
Category
Article
ISSN
1381-1169

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✍ Xiao-Yue Ouyang; Huan-Feng Jiang; Jing-Mei Huang 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 67 KB 👁 2 views

## Abstract It was found that __tert__‐BuNH~2~ is an efficient catalyst for epoxidation of __α__,__β__‐unsaturated ketones with 30% H~2~O~2~ under mild conditions. For most of the cyclic unsaturated ketones used, moderate to excellent yields (45%–93%) were obtained within 24 h period.