The chemical potential for dilute hard-sphere mixtures
β Scribed by C. Seiter; B. J. Alder
- Publisher
- Springer US
- Year
- 1978
- Tongue
- English
- Weight
- 259 KB
- Volume
- 7
- Category
- Article
- ISSN
- 0095-9782
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π SIMILAR VOLUMES
An efficient method for calculating the chemical potential of hard sphere fluids up to high densities by computer simulation is extended to the case of fluids of hard homonuclear and heteronuclear diatomics. The chemical potentials have been simulated at packing fractions up to 7/= 0.45 and used to
The properties of the electronic chemical potential, Jo and the chemical hardness, 7, are summarized. Rulesof-thumb are given for predicting the changes in p and 77 when small subsystems are combined to form larger systems. In general, the hardness increases when the energy decreases. Covalent bondi