## Abstract The deuterium isotope partition coefficient α has been determined as a function of total pressure, temperature and degree of deuteriation for methylcyclohexane/hydrogen over Ni/Al~2~O~3~. Good agreement with theory has been obtained for the dependence on temperature but not for that on
✦ LIBER ✦
The Chemical Ionization of Organic Compounds. 2nd Communication. Linear Alkyl Halides
✍ Scribed by Raymond Houriet; Tino Gäumann
- Publisher
- John Wiley and Sons
- Year
- 1976
- Tongue
- German
- Weight
- 335 KB
- Volume
- 59
- Category
- Article
- ISSN
- 0018-019X
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✦ Synopsis
Abstract
The chemical ionization spectra of linear alkyl halides with up to nine carbon atoms have been studied using water as protonating agent. An alkyl ion with the same number of carbon atoms as the halide is produced. With more than six carbon atoms in the chain, fragmentation becomes important. The results show that excited hydronium ions participate as intermediates and the fragments of the resulting alkyl ions have branched structures.
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