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The chemical effect in surface enhanced Raman scattering (SERS) for piperidine adsorbed on a silver electrode

โœ Scribed by A. Kudelski; J. Bukowska


Book ID
117216854
Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
320 KB
Volume
368
Category
Article
ISSN
0039-6028

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Herein we report Raman signals, enhanced greater than 10 5 -fold, from citrate ion adsorbed on colloidal silver. Al though this confirms our recently formulated theoretical model 1,2 in that SERS comparable to that observed on roughened macroscopic surfaces 3 also occurs in colloidal dispersions, 4

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SERS from crystal rlolct (CV) on a Ag clectrodc was mvcslqakd under prcrrsonsncc and resonance condltlons. The ckcll~llon prolilc of the chcmaorbcd spccics is Me that of chsrolvcd mokculcs but mtcnsltirs ZUIL' =I000 tnncs luger. The Raman enhancement IS = IO8 and ckhlblts 3 spcc~lic potcntlal dcpcnd