✦ LIBER ✦

The cathodic reduction of o-halonitrobenzenes in acidic propanol/water

✍ Scribed by Jairo Marquez; Derek Pletcher

Publisher: Elsevier Science
Year: 1981
Tongue: English
Weight: 355 KB
Volume: 26
Category: Article
ISSN: 0013-4686
DOI: 10.1016/0013-4686(81)85160-2

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✦ Synopsis

The electrochemical reduction of three o-halonitrobenzenes at mercury in acidic 50% npropanol/water has been studied and compared with that of nitrobenzene. The objective of this study was to seek conditions for the complete 6e reduction to the corresponding anilines; with the fluoro-and chlorocompounds thiscould be achieved in yields exceeding 75 p; and at current densities above 100 mA cm-* using 0.1 M H,SO, as the electrolyte. With o-bromonitrobenezene the yield was lower because of competing cleavage of the GBr bond.

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