THE CATALYTIC DECOMPOSITION OF AZOMETHANE, SYM.-DIMETHYLHYDRAZINE, AND MONOMETHYLAMINE: THE THERMAL DECOMPOSITION OF SYM.-DIMETHYLHYDRAZINE
β Scribed by Emmett, P. H.; Harkness, R. W.
- Book ID
- 127333168
- Publisher
- American Chemical Society
- Year
- 1932
- Tongue
- English
- Weight
- 644 KB
- Volume
- 54
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
Ihe thermal decomposition of azomethane-d6 has been studied. There is a short chain reaction, and measurements have been made of the rate of production of N, , CD, , and C,D, . .\ mechanism is suggested which accounts for these results fairly well. A com- parison is made with some similar results of
The rate constants (kuni) for the first-order disappearance of the title molecules have been determined under VLPP conditions. The kuni are not the rate constants of ultimate interest since they reflect the fact that energy transfer competes with the chemical decomposition. Use of the Rice-Ramsperge