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The Catalytic Asymmetric Claisen Rearrangement (CAC) in Natural Product Synthesis: Synthetic Studies Toward Curvicollides A—C.

✍ Scribed by Marleen Koerner; Martin Hiersemann

Book ID
101984846
Publisher
John Wiley and Sons
Year
2006
Weight
25 KB
Volume
37
Category
Article
ISSN
0931-7597

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✦ Synopsis

Other natural products U 0800

The Catalytic Asymmetric Claisen Rearrangement (CAC) in Natural Product Synthesis: Synthetic Studies Toward Curvicollides A-C. -A highly enantioselective approach to the ketone (V), the C8-C12 building block of curvicollides A-C (VI), includes asymmetric Claisen rearrangement of vinyl ether (II) and stereoselective reduction of the keto ester (III). -(KOERNER, M.; HIERSEMANN*, M.; Synlett

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