The Catalytic Activity of Thiourea and Thiourea Analogues in the Rearrangement of Maleic Acid to Fumaric Acid
β Scribed by Dr. W. Schliesser
- Publisher
- John Wiley and Sons
- Year
- 1962
- Tongue
- English
- Weight
- 115 KB
- Volume
- 1
- Category
- Article
- ISSN
- 0044-8249
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β¦ Synopsis
observed at ordinary temperatures only in the Li20-U205 system, it may be assumed that in this case stabilized U205 is present due to incorporation of very small amounts of LizO. With very low amounts of Liz0 (1 LizO: 15-20 U2O5), the lines of the hexagonal modification diverge in the direction of the lines of the orthorhombic a-U308 modification, and at the same time UO2.25 lines make their appearance in the Xray photograph. The compounds MgO.U205 and CdO.Uz05 crystallize in a fluorite-type lattice with statistical distribution of the cations
π SIMILAR VOLUMES
The [4 2] cycloaddition of cyclopentadiene to the (2R )-bornane-10,2-sultam derivative (Γ)-1b of fumaric monomethyl ester proceeds with high endo and p-facial diastereoselectivity in the presence of 0.5 mol-equiv. of TiCl 4 . The major diastereoisomer endo-(2R,3R )-2b, isolated in 87% yield by cryst