Kinetics of iron and copper catalysis of
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K.A. Skov; D.J. Vonderschmitt
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Article
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1975
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Elsevier Science
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The effects of oxidant, pH and ligands on iron- and copper-catalyzed ascorbate oxidation have been examined. The formation of the catalyst-substrate complex is affected by pH, whereas oxidant affects its breakdown. With copper-ion catalysis, ligands inhibit competitively. With iron catalysis, on the