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The Carboxylation of cis- and trans-2-Butenyl-2-lithium. A Stereospecific Synthesis of Angelic Acid 1

โœ Scribed by Dreiding, Andre S.; Pratt, Richard J.


Book ID
121356086
Publisher
American Chemical Society
Year
1954
Tongue
English
Weight
720 KB
Volume
76
Category
Article
ISSN
0002-7863

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A preparative route to cis-and trans-1,2-dibromocyclopropane ' Trans-& b.p. (120ยฐC/300 mbar) and H NMR spectrum were In agreement with the literature 2 ; w m.p. 8OC; b.p. 120ยฐC/100 mbar; 'H NMR spectrum (CDC13, 250 Mhz): 6 = 3.10 ppm (dd,