Dialkylcyanocuprates, prepared from copper(l) cyanide and the corresponding alkyllithium or Gringard reagents, readily react with carbon monoxide in the presence of tri-n-butylphosphine at -78 "C in THF to give a-hydroxyketones in high yields (6585%). Q 1997 Elsevier Science Ltd.
✦ LIBER ✦
The carbonylation ofα,Β′-bipiperidyl with carbon monoxide
✍ Scribed by Ya. Yu. Aliev; I. B. Romanova; Z. F. Panfilova
- Book ID
- 112395543
- Publisher
- Springer US
- Year
- 1970
- Tongue
- English
- Weight
- 114 KB
- Volume
- 4
- Category
- Article
- ISSN
- 0009-3122
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## Abstract 4,6‐Diaminoresorcinol, which is a raw material of ZYLON (PBO fiber), has an instability in air atmosphere. Therefore, very stable benzo[1,2‐d:5,4‐d']bis‐2(3H)‐oxazolone recognized a useful equivalent of 4,6‐diaminoresorcinol during the stages of production, storage, and transportation.