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The capacity of the HgHClO4 · 5.5H2O interface in the liquid-liquid, solid-liquid and solid-solid state Temperature and potential dependence

✍ Scribed by Marcella Cappadonia; H. Thomas von der Heyden; Ulrich Stimming

Publisher: Elsevier Science
Year: 1997
Tongue: English
Weight: 596 KB
Volume: 94
Category: Article
ISSN: 0167-2738
DOI: 10.1016/s0167-2738(96)00599-1

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✦ Synopsis

The interface Hg/HCIO, .5SH,O was investigated by cyclic voltammetry and electrochemical impedance spectroscopy between 170 and 300 K. In this temperature range, phase transitions occur for electrode and electrolyte, such that within 6 K the electrode-electrolyte interface changes from solid-solid over solid-liquid to liquid-liquid or vice versa. The double layer capacity was investigated as a function of potential for different temperatures and states of aggregation of the respective phases.

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