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The C-H stretching bands of methyl groups attached to polycyclic aromatic hydrocarbons

✍ Scribed by G.M. Badger; A.G. Moritz


Publisher
Elsevier Science
Year
1959
Weight
429 KB
Volume
15
Category
Article
ISSN
0371-1951

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✦ Synopsis


The infrared spectra of a number of methyl substituted polycychc aromatic hydrocarbons have been obtained in the 3000-2700 cm-' region. An apparent correlation is shown to e&t with the spectra in this region and the free valence number for the position of substitution m the parent hydrocarbon.

The possibility of steric effects determining this correlation is considered. introduction FUSON and JOSIEN [l] examined the infrared spectra of the twelve mono methyl-1:2 benzanthracenes and found that the overall appearance of the 3000 cm-l region was similar for methyl groups attached to the low free valence index carbon atoms. The intermediate index isomers, however, were found to show much variety among


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