The B̃1A2 ← X́1A1 absorption spectrum of thioformaldehyde

✍ Scribed by C.R. Drury; J.Y.K. Lai; D.C. Moule

• Publisher: Elsevier Science
• Year: 1982
• Tongue: English
• Weight: 168 KB
• Volume: 87
• Category: Article
• ISSN: 0009-2614
• DOI: 10.1016/0009-2614(82)83169-2

✦ Synopsis

Rccewcd ?. J~nuxy 1982 The n -n* Jbsorprlon spectrum oi rhioformaldchydc has been recorded at rebtwly high pressures and path lengths The system IS qultc cucnwc and m H,CS drsplays a progrcsslon oi bands m an mtcrwl of 476 cm-' which can be followcd out to u' = 12. This IS assgncd IO Ihc V\ CS strctchmg mode. A second wcticr set of bands IS assgncd IO 5;. the outoi-phne bendq mode. The 725 cm-' inrewd observed here compucd to the 711 cm-' value oi the rstatc leads us IO 111~ conclusron that [he bxrlcr lo mverslon IS less than 50 cm-l.