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The “Building-Block” Assembly of a [Ni12Mn6] Aggregate (Eur. J. Inorg. Chem. 10/2006)

✍ Scribed by Gang Wu; Rodolphe Clérac; Wolfgang Wernsdorfer; Shilun Qiu; Christopher E. Anson; Ian J. Hewitt; Annie K. Powell


Book ID
102169144
Publisher
John Wiley and Sons
Year
2006
Tongue
English
Weight
69 KB
Volume
2006
Category
Article
ISSN
1434-1948

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The “Building-Block” Assembly of a [Ni12
✍ Gang Wu; Rodolphe Clérac; Wolfgang Wernsdorfer; Shilun Qiu; Christopher E. Anson 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 150 KB

## Abstract Reaction of Mn^II^(bdoa)(H~2~O)~3~ with Ni(CH~3~COO)~2~·3H~2~O in methanol gives a heterometallic cluster, [Ni~12~Mn~6~(bdoa)~6~(O~2~CMe)~12~(μ~3~‐OMe)~12~(MeOH)~12~]·21MeOH, which was structurally characterised by single‐crystal X‐ray diffraction and possesses three self‐assembled tetr