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THE BROMO DERIVATIVES OF 1,4-DIMESITYLBUTANE-1,2,4-TRIONE ENOL

✍ Scribed by LUTZ, ROBERT E.; TERRY, DANIEL H.

Book ID
120273609
Publisher
American Chemical Society
Year
1942
Tongue
English
Weight
399 KB
Volume
07
Category
Article
ISSN
0022-3263

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ChemInform Abstract: Reaction of Ethyl 4
ChemInform Abstract: Reaction of Ethyl 4,4,4-Trifluoroacetoacetate Enolate with 3-Bromo-1,1, 1-trifluoroacetone: Synthesis of 2,4-Bis(trifluoromethyl)furan.
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Reaction of Ethyl 4,4,4-Trifluoroacetoacetate Enolate with 3-Bromo-1,1, 1-trifluoroacetone: Synthesis of 2,4-Bis(trifluoromethyl)furan. -The title reaction follows competing courses such as C-acylation, O-alkylation and di-O-alkylation which result in the formation of two major products (III) and (I