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The broadening of d–f and f–d transitions by collisions with neutral hydrogen atoms

✍ Scribed by Barklem; O'Mara; Ross

Publisher
John Wiley and Sons
Year
1998
Tongue
English
Weight
413 KB
Volume
296
Category
Article
ISSN
0035-8711

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Dependence of relativistic effects on el
Dependence of relativistic effects on electronic configuration in the neutral atoms of d- and f-block elements
✍ J. Autschbach; S. Siekierski; M. Seth; P. Schwerdtfeger; W. H. E. Schwarz 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 229 KB 👁 1 views

Although most neutral d- and f-block atoms have nd(g-2)(n + 1)s(2) and (n - 1)f(g-2)(n + 1)s(2) ground configurations, respectively, where g is the group number (i.e., number of valence electrons), one-third of these 63 atoms prefer a higher d-population, namely via (n + 1)s-->nd "outer" to "inner"