Symmetry and group theory provide us with a rigorous method for the description of the geometry of objects by describing the patterns in their structure. In chemistry it is a powerful concept that underlies many apparently disparate phenomena. Symmetry allows us to accurately describe the types of b
The breaking of molecular point group symmetry
β Scribed by P. R. Bunker
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 2010
- Weight
- 413 KB
- Volume
- 89
- Category
- Article
- ISSN
- 0037-9646
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π SIMILAR VOLUMES
Geoffrey A. Lawrance. Includes Bibliographical References And Index.
We present a complete classification of symmetry-breaking terms in the one-and two-body densities for crystallographic space group P6 3 /mmc according to irreducible representations (IR) of the extended Euclidean space group E(|R 3 ) in three dimensions. We show that these IRs of E(|R 3 ) are the or
A reinvestigation of the microwave spectrum of tricarbonyl(cyclobutadiene) iron has revealed a new fine structure. This is not in agreement with previously published results. In this paper a first attempt of the appropriate description of the molecules internal dynamics is made.