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The boronic acid Mannich reaction in alkaloid synthesis

✍ Scribed by Pyne, Stephen G. (author);Davis, Andrew S. (author);Ritthiwigrom, Thunwadee (author);Au, Christopher W.G. (author);Savaspun, Kongdech (author);Wotherspoon, Matthew (author)

Book ID
124161699
Publisher
International Union of Pure and Applied Chemistry
Year
2012
Tongue
English
Weight
719 KB
Volume
85
Category
Article
ISSN
0033-4545

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The boronic acid Mannich reaction in alk
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N-1-(Carbamate protected)-N-2-(alkyl or aryl substituted) hydrazines can serve as amine substrates for the Petasis boronic acid-Mannich reaction, providing a practical synthetic route for the preparation of a-hydrazinocarboxylic acids. The scope and limitations of this method have been examined.