The bond between inverted carbon atoms. Synthesis and chemistry of 2,4-methano-2,4-didehydroadamantane: a highly reactive [3.1.1]propellane
β Scribed by Mlinaric-Majerski, Katica; Majerski, Zdendo
- Book ID
- 121277691
- Publisher
- American Chemical Society
- Year
- 1983
- Tongue
- English
- Weight
- 1014 KB
- Volume
- 105
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
Palladium-catalyzed carbomethoxylation of benzonorbornadiene (7) yielded dimethyl-1.4methano-l,2.3.4-tetrahydronaphthalene-2,3-dicarboxylate (9) which was transformed in three steps into 2.3-dimethylene-l,4-methano-l.2,3.4-tetrahydronaphthalene (4) in a high yield. Reaction of 4 with singlet oxygen
Tetrahydro-1,2-dimethylidenenaphthalene 11 has been derived in three steps from tetralone. In the condensed state and at Γ 808, it undergoes a highly chemo-and regioselective cyclodimerization to give 3,3',4,4'tetrahydro-2-methylidenespiro[naphthalene-1(2H),2'(1'H)-phenanthrene] ( 14), the structure