๐”– Bobbio Scriptorium
โœฆ   LIBER   โœฆ

The Biotransformation of 4-Oxa- and 6-Oxa-5a-androstan-17-one by Mucor Plumbeus.

โœ Scribed by Khaled Al-Fouti; James R. Hanson


Publisher
John Wiley and Sons
Year
2003
Weight
53 KB
Volume
34
Category
Article
ISSN
0931-7597

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## Abstract Ethyl 4โ€oxoalkanoates 1 react at ambient temperature in dry methanol in the presence of molecular sieve 3 ร… in almost quantitative yield with 3โ€aminopropanol and 2โ€aminoethanol to form the bicyclic lactams __rac__โ€2 and __rac__โ€3, respectively. Surprisingly, the (ยฑ)โ€5โ€alkylโ€4โ€oxaโ€1โ€azab