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The biosynthesis of valanimycin. Further evidence for the intermediacy of a hydroxylamine in N-N bond formation

โœ Scribed by Parry, Ronald J.; Li, Wenying


Book ID
121011189
Publisher
The Royal Society of Chemistry
Year
1994
Tongue
English
Weight
253 KB
Volume
8
Category
Article
ISSN
0022-4936

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N-(2-immo, 1-oxo-propyl)-glycine are readily formed as intermediates in the base-catalyzed decomposition of (N-X)-Ala-GIy. These compounds suffer a subsequent hydrolysis to the corresponding N-(l,2-dioxo-propyl)-glycine.