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The Binuclear Cyclopentadienylvanadium Carbonyls (η5-C5H5)2V2(CO)7 and (η5-C5H5)2V2(CO)6: Comparison with Homoleptic Chromium Carbonyls

✍ Scribed by Xiuhui Zhang; Qian-shu Li; Yaoming Xie; R. Bruce King; Henry F. Schaefer III


Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
182 KB
Volume
2007
Category
Article
ISSN
1434-1948

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The ionized states of [CO~(~~-C~H,)~(CO)~] and [Co,($-C,H,),(NO),] are investigated by a CI method which allows for electron reorganization, positive hole localization, and includes part of the correlation energy. Qualitative bonding schemes and the photoelectron spectra are discussed in terms of th