The Binding Energy and Bonding in Dialane
β Scribed by Goebbert, Daniel J.; Hernandez, Heriberto; Francisco, Joseph S.; Wenthold, Paul G.
- Book ID
- 126249205
- Publisher
- American Chemical Society
- Year
- 2005
- Tongue
- English
- Weight
- 154 KB
- Volume
- 127
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
Extended basis set calculations yield a dissociation energy AhE(MeLi --, Me + Li) = 46.4 f 1.2 kcal mol -'. The Me-Li bond has non-negligible covalent contributions. Comparison with the series of molecules NaF, NaCI, LiF and LiCl shows that the covalent contribution in MeLi is more pronounced than i
Binding energies and bond distances are calculated with the semiempirical MO method SINDO 1. A quasilinear relationship is found between normalized binding energies or average bond distances and relative average coordination numbers. It is demonstrated that binding energy per unit and binding energy