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The behaviour of the AsCo3(CO)9cluster as a ligand for Cr, Mo, W, and Fe carbonyls and AlCl3

✍ Scribed by Anna Vizi-Orosz; Vilmos Galamb; Irma Ötvös; Gyula Pályi; László Markó


Publisher
Springer
Year
1979
Tongue
English
Weight
372 KB
Volume
4
Category
Article
ISSN
0340-4285

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The 1,3-Sn2O2-Heterocycle as a Ligand in
✍ Peter Kircher; Gottfried Huttner; Katja Heinze; Laszlo Zsolnai 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 500 KB

## Dimerized inidene complexes [(CO) 5 M … Ϫ Sn(OR) … Ϫ M(CO) 5 ] 2 2system, which characterizes monomeric inidene species still prevalent in the dimeric species 1. The (M = Cr, W; R = Et, iPr), 1, are obtained from [{(CO) 5 M} 2 SnCl 2 ] 2- by different routes. Dimerization occurs via alkoxy-don