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The behaviour of high polar organic solvents at platinum electrode — II. Adsorption and electrode reactions of acetonitrile

✍ Scribed by Marek Szklarczyk; Jerzy Sobkowski

Publisher
Elsevier Science
Year
1980
Tongue
English
Weight
410 KB
Volume
25
Category
Article
ISSN
0013-4686

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✦ Synopsis

The adsorption of acetonitrile and reduction of adsorbed molecules at platinized platinum electrode were studied by potentiodynamic and radiometric techniques. During acetonitrile adsorption the reversibly and irreversibly adsorbed species are formed. One electron reduction process occurs in the potential range 0.45-0.15 V. Below 0.15 V the deeper reduction of adsorbed acetonitrilc takes place-the final Droducts are ammonia and ethane. The differences of smooth and platinized platinum electrodes properties ire briefly discussed.

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