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The Baylis-Hillman reaction: An expedient synthesis of (Z)-keto allyl bromides and chlorides

✍ Scribed by Deevi Basavaiah; Rachakonda Suguna Hyma; Kisari Padmaja; Marimganti Krishnamacharyulu

Publisher
Elsevier Science
Year
1999
Tongue
French
Weight
349 KB
Volume
55
Category
Article
ISSN
0040-4020

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✦ Synopsis

A simple and expedient synthesis of (Z)-keto allyl bromides and chlorides, from the Baylis-Hillman adduets is described.

📜 SIMILAR VOLUMES

ChemInform Abstract: Facile Stereoselect
ChemInform Abstract: Facile Stereoselective Synthesis of (E)- and (Z)-Allyl Bromides from the Baylis—Hillman Adducts Using MgBr2.
✍ Subramanian Ravichandran 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 31 KB 👁 2 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v

A Rapid and Efficient Stereoselective Sy
A Rapid and Efficient Stereoselective Synthesis of (Z)- and (E)-Allyl Bromides from Baylis–Hillman Adducts Using Bromo(dimethyl)sulfonium Bromide
✍ Biswanath Das; Katta Venkateswarlu; Maddeboina Krishnaiah; Harish Holla; Anjoy M 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 German ⚖ 78 KB

Treatment of Baylis-Hillman adducts 1 with bromo(dimethyl)sulfonium bromide, Br(Me 2 )S + Br À , in MeCN was found to stereoselectively afford (Z)-and (E)-allyl bromides 2. The reaction is rapid at room temperature, high-yielding, and highly stereoselective.

ChemInform Abstract: An Expedient Synthe
ChemInform Abstract: An Expedient Synthesis of 2-Substituted Naphthalenes from the Baylis—Hillman Adducts.
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v

Studies on Novel Synthetic Methodologies
Studies on Novel Synthetic Methodologies. Part 81. A Rapid and Efficient Stereoselective Synthesis of (Z)- and (E)-Allyl Bromides from Baylis—Hillman Adducts Using Bromo(dimethyl)sulfonium Bromide.
✍ Biswanath Das; Katta Venkateswarlu; Maddeboina Krishnaiah; Harish Holla; Anjoy M 📂 Article 📅 2006 🏛 John Wiley and Sons ⚖ 19 KB 👁 2 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.