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The base-induced decomposition of peroxyacetylnitrate

โœ Scribed by R.P. Steer; K.R. Darnall; J.N. Pitts Jr.

Book ID
104239834
Publisher
Elsevier Science
Year
1969
Tongue
French
Weight
158 KB
Volume
10
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

Peroxyacetylnitrate

(PAN), a highly reactive, biologically important photochemical air pollutant (l), decomposes in the presence of base (2,3) according to reaction 1. Whereas this stoichiometrically correct reaction in no way sug-.O

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The base-induced decomposition of N-nitr
The base-induced decomposition of N-nitroso-N-methylurea
โœ Sidney M. Hecht; John W. Kozarich ๐Ÿ“‚ Article ๐Ÿ“… 1972 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 245 KB

To date three mechanisms have been proposed for the base-induced decomposition of N-nitroso-N-alkylureas. A mechanism involving initial nucleophilic attack on the carbonyl moiety of the urea (Scheme I) had been assumed 1\*2 to be correct, by analogy with the