✦ LIBER ✦

The Base-Catalyzed Self-Condensation of α,β-Unsaturated Ketones. Structure of Heilbron's Styryl Alkyl Ketone Dimers 1

✍ Scribed by Nielsen, Arnold T.; Dubin, Henry J.

Book ID: 126493658
Publisher: American Chemical Society
Year: 1963
Tongue: English
Weight: 706 KB
Volume: 28
Category: Article
ISSN: 0022-3263
DOI: 10.1021/jo01043a044

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Base-Catalyzed Condensations of Aldehyde

Base-Catalyzed Condensations of Aldehydes with α,β-Unsaturated Ketones 1

✍ Powell, Sargent G.; Wasserman, William J. 📂 Article 📅 1957 🏛 American Chemical Society 🌐 English ⚖ 703 KB

The Base-Catalyzed Self-Condensation of

The Base-Catalyzed Self-Condensation of α,β-Unsaturated Ketones. Condensation of Cyclopropyl Methyl Ketone with 2-Methylpropanal to Isomeric Diketones, C 18 H 28 O 21

✍ NIELSEN, ARNOLD T.; MOORE, DONALD W.; HIGHBERG, KRISTIN 📂 Article 📅 1961 🏛 American Chemical Society 🌐 English ⚖ 803 KB

Base-catalyzed intermolecular condensati

Base-catalyzed intermolecular condensation of .alpha.,.beta.-unsaturated ketones. Self-condensation of styryl isobutyl ketone to epimeric diketones, C26H32O2, and a triketone, C39H48O3. Stereochemistry of Michael cyclization

✍ Nielsen, Arnold T.; Moore, Donald W. 📂 Article 📅 1969 🏛 American Chemical Society 🌐 English ⚖ 1001 KB

The Structure of 1-Acetyl-2-methylcycloh

The Structure of 1-Acetyl-2-methylcyclohexene; Spectral Characteristics of s-cis-α,β-Unsaturated Ketones 1

✍ Turner, Richard B.; Voitle, Dorothy M. 📂 Article 📅 1951 🏛 American Chemical Society 🌐 English ⚖ 842 KB

Lewis acid catalyzed rearrangements of s

Lewis acid catalyzed rearrangements of structurally related α,β-unsaturated epoxy ketones and oximes. A complementary approach to the synthesis of isomeric 1,4-diketospiro[n,m] alkanes.

✍ Robert D. Bach; Mark W. Tubergen; Russell C. Klix 📂 Article 📅 1986 🏛 Elsevier Science 🌐 French ⚖ 246 KB

## Lew~'s acid catal.vzed rearrangement of cr,B-epoxy o.yimes proceeds b_v oxl'rane cleavage u to the oxime moiety with an attendant pinacol t_vpe alkyd roigration to the resonance stabilized carbenium ion at C, affording a I,_%d2'keto-monoxl'me. Recent mechanistic studies have provided cogent arg