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The Autoxidation of Methyl Oleate

✍ Scribed by Ross, John.; Gebhart, Arthur I.; Gerecht, J. Fred.

Book ID
120065862
Publisher
American Chemical Society
Year
1949
Tongue
English
Weight
719 KB
Volume
71
Category
Article
ISSN
0002-7863

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## Abstract Methyl oleate was oxidized at 60Β°C at free access of air in presence of varying amounts of copper(II)‐chloride. Changes of hydroperoxides followed equation (V):magnified image. The relationships between the two reaction rate constants and the concentration of copper(I1)ions are best ex

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A procedure is described demonstrating the formation of four hydroperoxide isomers in the autoxidation of methyl oleate in accordance with the free radical chain reaction concept of autoxidation. Experimental proof is also given for the location of the hydroperoxide group in the a-position relative