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The autooxidation of 2,3,5,6-tetrahydroxy-2,5-cyclohexadiene-1,4-dione under physiological conditions

✍ Scribed by M. E. Hoffmann; D. B. Ciampi; N. Duran


Publisher
Springer
Year
1987
Tongue
English
Weight
361 KB
Volume
43
Category
Article
ISSN
1420-682X

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## Abstract In contrast to earlier reported unsuccessful experiments the Michael addition of prop‐2‐enal to 2‐methylcyclopentane‐1,3‐dione (1) affords 3‐(1‐methyl‐2,5‐dioxocyclopentyl)propanal (3) in 90% yield, if the reaction is carried out in water without a basic catalyst. This aldehyde is conve