The attempted oxymercuration-demercuration of 2-phenylbornylene
β Scribed by J.M. Coxon; M.P. Hartshorn; A.J. Lewis
- Publisher
- Elsevier Science
- Year
- 1969
- Tongue
- French
- Weight
- 79 KB
- Volume
- 10
- Category
- Article
- ISSN
- 0040-4039
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π SIMILAR VOLUMES
The oxymercuration -demercuration of ethylene ketal of bicyclomet-2-en-8-one is reported. This reaction proceeds with high regio-and stereoselectivity.
The recent development of the oxymercuration-demercuration procedure1 has provided a convenient route from an olefin to its corresponding Markovnikov hydration product. We would like
Methyl oleate is converted in high yield to methyl 9(10)-methoxystearate by reaction with methanol in the presence of mercuric acetate followed by demercuration with sodium borohydride. Similar ethoxy-, hydroxy-, acetoxy-, acetylamino-, and hydroxyethoxystearates result when the nucleophilic solvent