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The atomic oxygen 1304 Å emission produced through photodissociation of CO and CO2

✍ Scribed by C.Y.Robert Wu; D.L. Judge


Publisher
Elsevier Science
Year
1979
Tongue
English
Weight
356 KB
Volume
68
Category
Article
ISSN
0009-2614

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✦ Synopsis


Atomic oxygen fluorescence radiation at 1304 A has been produced in the photoabsorption of extreme LJV radiation by CO and CO2 moIecuIes_ Absolute fluorescence production cross sections have been measured from threshold to 420 A (29.5 eV). The maximum cross section is 11-7 X IO-t9 cm* at 572 A for CO and ~1.6 X 10mzo cm2 at 718 A forCOZ_.


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CO laser emission at 5 pm was detected when SO2 and CFBr3 were flash photolyzed in the vacuum ultraviolet above 165 nm. Over 40 vibrational-rotational transitions ranging from Au = 2 -1 to 14 -13, with the exception of those between 8 -7 and 11 -10, were identified. The CO emission is believed to r