✦ LIBER ✦

The asymmetric synthesis of novel tin-functionalized carbapenam systems through radical cyclization of enyne β-lactams

✍ Scribed by Benito Alcaide; Jose L. Benito; Ignacio M. Rodríguez-Campos; Julián Rodríguez-López; Alberto Rodríguez-Vicente; Miguel A. Sierra; Santiago García-Granda; Angel Gutíerrez-Rodríguez

Publisher: Elsevier Science
Year: 1995
Tongue: English
Weight: 272 KB
Volume: 6
Category: Article
ISSN: 0957-4166
DOI: 10.1016/0957-4166(95)00123-7

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✦ Synopsis

New chiral, non-racemic, vinylstannyl carbapenams 2 are easily accessible by the regio-and stereocontrolled fin-mediated, vinyl radical intramolecular cyclization of enyne ~-lactams I.

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