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The aromatic cope rearrangement: Activation parameters

✍ Scribed by Elliot N Marvell; Stephen W Almond

Book ID
104237838
Publisher
Elsevier Science
Year
1979
Tongue
French
Weight
106 KB
Volume
20
Category
Article
ISSN
0040-4039

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πŸ“œ SIMILAR VOLUMES

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## An aromatic oxy-Cope rearrangement can be achieved under anionic conditions (KH f HMPAl in Zow yield with a nuphthalene ring but not a phenyt. We have recently measured the activation parameters for an aromatic Cope rearrangement,l and these sug,oest that rearrangement of 4-phenyl-1-butene wou

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oily liquid, later identified as 1. was collected ;it 80-85 'C at 1.3 kPa pressure in a detachable U-trap held at 0 C (1.02 g, 2.96 mmol. 37%). After further heating of the gray residue at 110-120 C in vdcuo. a colorless transparent crystalline solid, identified as 2. sublimed out of the reaction fl