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The application of the new type grignard reagent derived from ethyl α-(tert-butylsulfinyl)acetate to the synthesis of α,β-unsaturated esters.

✍ Scribed by Junzo Nokami; Norio Kunieda; Masayoshi Kinoshita

Book ID: 104214018
Publisher: Elsevier Science
Year: 1975
Tongue: French
Weight: 163 KB
Volume: 16
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)72671-2

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✦ Synopsis

Recently, we have reported that a new type Grignard reagent derived from ethyl a-phenylsulfinylacetate and alkylmagnesium halides has a good reactivity at the a-carbon atom toward aldehydes and ketones to give the corresponding

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