The application of the forsén-hoffman method of measuring rates of exchange to the 13C NMR spectrum of cis-decalin
✍ Scribed by Brian E Mann
- Publisher
- Elsevier Science
- Year
- 1976
- Weight
- 373 KB
- Volume
- 21
- Category
- Article
- ISSN
- 0022-2364
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📜 SIMILAR VOLUMES
## Abstract The slow exchange 360 MHz ^1^H NMR spectra of __cis__‐__transoid__‐__cis__‐perhydroanthracene and of __cis__‐decalin have been assigned. Shift increments due to the __cis__‐annelation of a tetramethylene bridge to cyclohexane are presented.
## Abstract The rates of interconversion of the __cis__ and __trans__ rotational isomers of __N__‐trifluoroacetyl‐__N__‐methylbenzylamine have been determined by a variety of NMR lineshape experiments and by several double resonance methods. Comparison of the results for the slow exchange region su
A new 13C N M R method based on solvent effects allows the identification of carbon atoms a to a carbonyl group. With a simple change in solvent from CDCl, to CDC1,-dioxane (1:4), the -C absorption for all carbons except those a to the carbonyl group in the compounds under study were displaced to lo